应用表面与胶体化学教育部重点实验室

成立十周年学术报告

（第 25 号）

报告题目：Production and Usage of Solar Liquid Fuels

报告人：Prof. Shunichi Fukuzumi

Department of Chemistry and Nano Science, Ewha Womans University，Korea

主持人：张伟强 副教授

报告时间：2017年9月22日（星期五）上午10:00

报告地点：致知楼1568

报告摘要：

Sustainable and clean energy resources using solar energy are urgently required in order to solve global energy and environmental issues. This lecture focuses on the combination of production of liquid fuels such as formic acid and hydrogen peroxide using solar energy, so called solar liquid fuels rather than gaseous hydrogen, and their use in direct liquid fuel cells.¹ In particular, photocatalytic production of hydrogen peroxide (H₂O₂) from seawater and dioxygen (O₂) in the air as a solar fuel is combined with its use in one compartment hydrogen peroxide fuel cells.

    We have developed a variety of photosynthetic reaction center models composed of organic electron donors and acceptors linked by covalent or non-covalent bonding, which undergo efficient charge separation and slow charge recombination.² The efficient charge-separation step has been successfully combined with the catalytic water reduction step with earth-abundant metal catalysts to develop efficient photocatalytic hydrogen evolution systems.³ The photocatalytic oxidation of water with O₂ in the air to produce H₂O₂ has been achieved,^4,5 together with the development of H₂O₂ fuel cells.^6,7 The photocatalytic oxidation of water with O₂ in the air was found to be enhanced significantly in seawater.⁸ Thus, the combination of the photocatalytic H₂O₂ production from seawater and O₂ using solar energy with one-compartment H₂O₂ fuel cells provides on-site production and usage of H₂O₂ as a more useful and promising solar fuel than H₂.^8,9  

References

(1)     S. Fukuzumi, Joule, 2017, 1, in press.

(2)     S. Fukuzumi, K. Ohkubo, T. Suenobu, Acc. Chem. Res., 2014, 47, 1455-1464.

(3)     S. Fukuzumi, D. Hong, Y. Yamada, J. Phys. Chem. Lett., 2013, 4, 3458-3467.

(4)     S. Kato, J. Jung, T. Suenobu, S. Fukuzumi, Energy Environ. Sci., 2013, 6, 3756-3764.

(5)     Y. Yamada, S. Yoshida, T. Honda, S. Fukuzumi, Energy Environ. Sci., 2011, 4, 2822-2825.

(6)     Y. Yamada, M. Yoneda, S. Fukuzumi, Energy Environ. Sci.,

(7)     K. Mase, M. Yoneda, Y. Yamada, S. Fukuzumi, ACS Energy Lett., 2016, 1, 913-919. 2015, 8, 1698-1701.

(8)     K. Mase, M. Yoneda, Y. Yamada, S. Fukuzumi, Nat. Commun., 2016, 7, 11470.

(9)     S. Fukuzumi, Y.-M. Lee, W. Nam, ChemSusChem, 2017, 10, in press.

报告人简介：

Shunichi Fukuzumi

Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea, Faculty of Science and Technology, Meijo University, Nagoya, Japan

E-mail: fukuzumi@chem.eng.osaka-u.ac.jp

Education:  Ph. D. (March, 1978), M. Eng. (March, 1975), B. Eng. (March, 1973): Tokyo Institute of Technology

Academic Carrier:

1978 (April)-1981 (March):  Post-doctoral fellow, Department of Chemistry, Indiana University (supervisor: Prof. Jay K. Kochi)

1981 (April):  Assistant Professor, Department of Applied Chemistry, Faculty of Engineering, Osaka University

1992 (August):  Associate Professor, Department of Applied Chemistry, Faculty of Engineering, Osaka University

1994 (May):  Professor, Department of Applied Chemistry, Faculty of Engineering, Osaka University

1995 (April)-: Professor, Department of Material and Life Science, Graduate School of Engineering, Osaka University

2013 (July): Distinguished Professor, Osaka University

2015 (April): Distinguished Professor, Ewha Womans University; Professor Emeritus, Osaka University; Designated Professor, Meijo University

Invited Professor:

Université de Droit, D’Economie et des Sciences D’Aix-Marseille, Faculte des Sciences et Techniques de Saint-Jerome, 1989, Department of Chemistry, Ecole Normale Superieure, 1998, Faculté des Sciences Gabriel, Université de Bourgogne, 2001-2004., University of Strasbourg, 2010.

Award: The Chemical Society of Japan (CSJ) Award (2005), Osaka University Award (2005), Bull. Chem. Soc. Jpn. Award (2006), Honorary Degree from Tampere University of Technology, Finland (2007), The Commendation for Science and　Technology by the Minister of Education, Culture, Sports, Science and Technology (2010), The Japanese Photochemistry Association Special Lectureship Award (2011), Medal with Purple Ribbon from the Emperor (2011), NIMS Award (2012), Roseman Award (2012), KAIST Lectureship Award (2012), Distinguished Professorship of Osaka University (2013), Robert Burns Woodward Career Award in Porphyrin Chemistry, The Society of Porphyrins and Phthalocyanines (2014), Physical Organic Chemistry Award (2014), Asian and Oceanian Photochemistry Association (APA) Award (2016), AsBIC Outstanding Achievement Award (2016), Richard Smalley Research Award - The Electrochemical Society (2017).

Research Area:  Artificial Photosynthesis, Electron Transfer Chemistry, Redox Catalysis

Paper: 1162 (Web of Science), Citation: 39,725, h-index: 98.

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