研究队伍

教授

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李兴伟

发布人：  发布时间：2019-08-15  点击：[]

 

李兴伟 教授

Prof. Xingwei Li

Tel:   +86-29-81538783

E-mail:   lixw@snnu.edu.cn

 

学习及工作经历（从博士开始）：

耶鲁大学 博士（2001-2005）

加州理工学院 博士后 (2005-2006)

新加坡南洋理工大学 助理教授（2006-2008）

美国Scripps 研究所 研究助理教授 (2008-2009)

中国科学院大连化学物理研究所 研究员 (2010-2018）

陕西师范大学 教授（2018年至今）

Educations and Work Experiences：

Ph.D., Yale University（2001-2005）

Postdoc, California Institute of Technology (2005-2006)

Assistant Professor, Nanyang Technological University (Singapore, 2006-2008）

Assistant Professor of Catalysis, Scripps Florida (TRSI) (2008-2009）

Professor, Dalian Institute of Chemical Physics, CAS (2010-2018)

Prof. Shaanxi Normal University (since 2018)

研究领域：

均相催化

有机合成发法学

金属有机化学

Research interests:

Homogeneous Catalysis

Synthetic Organic Chemistry

Organometallic Chemistry

代表性成果（Representative Publications，包括论文、专利、著作等）

 

1.       “Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C-H Activation and Ring Opening” Xukai Zhou, Songjie Yu, Lingheng Kong, Xingwei Li*, ACS Catal. 2016, 6, 647-651.

2.        “Rhodium(III)-Catalyzed Annulation between N-Sulfinyl Ketoimines and Activated Olefins: C-H Activation Assisted by an Oxidizing N-S Bond” Qiang Wang, Yingzi Li, Zisong Qi, Fang Xie, Yu Lan,* Xingwei Li* ACS Catal. 2016, 6, 1971-1980. (ESI highly cited)

3.       “Redox-Neutral Couplings between Amides and Alkynes via Cobalt(III)-Catalyzed C-H Activation” Lingheng Kong, Songjie Yu, Fang Xie, Xingwei Li*, Org. Lett. 2016, 18, 588-591. (ESI highly cited)

4.       “Rh(III)-Catalyzed Synthesis of N-Unprotected Indoles from Imidamides and Diazo Ketoesters via C-H Activation and C-C/C-N Bond Cleavage” Zisong Qi, Songjie Yu, Xingwei Li*, Org. Lett. 2016, 18, 700-703.

5.       “Co(III)-Catalyzed Synthesis of Quinazolines via C-H Activation of N-Sulfinylimines and Benzimidates” Fen Wang, He Wang, Qiang Wang, Xingwei Li*, Org. Lett. 2016, 18, 1306-1309.

6.       “Anthranil: an Aminating Reagent for Both sp3 and sp2 C-H Bonds Leading to Bifunctionality under Rhodium(III) Catalysis” Songjie Yu, Guodong Tang, Yingzi Li, Xukai Zhou, Yu Lan*, Xingwei Li*, Angew. Chem. Int. Ed. 2016, 55, 8696-8700.

7.       “Synthesis of 1H-Indazoles from Imidates and Nitrosobenzenes via Synergistic Rhodium/Copper Catalysis” Qiang Wang and Xingwei Li,* Org. Lett. 2016, 18, 2102-2105.

8.        “Efficient Access to Structurally Diverse Quinoline-Fused Heterocycles via Rhodium(III)-Catalyzed C-C/C-N Coupling of Bifunctional Substrates” Songjie Yu, Yunyun Li, Xukai Zhou, He Wang, Lingheng Kong, Xingwei Li*, Org. Lett. 2016, 18, 2812-2815. (highlighted by Synfacts)

9.       “Rh(III)-Catalyzed C-C/C-N Coupling of Imidates with alfa-Diazo Imidamide: Synthesis of Isoquinoline-Fused Indoles” He Wang, Lei Li, Songjie Yu, Yunyun Li, Xingwei Li*, Org. Lett. 2016, 18, 2914-2917.

10.   “Cobalt(III)-Catalyzed C-C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C-H Activation” Lingheng Kong, Songjie Yu, Guodong Tang, He Wang, Xukai Zhou, Xingwei Li* Org. Lett. 2016, 18, 3802-3805.

11.  “Cooperative Co(III)/Cu(II)-Catalyzed C-N/N-N Coupling of Imidamides with Anthranils: Access to 1H-Indazoles via C-H Activation” Lei Li, He Wang, Songjie Yu, Xifang Yang, Xingwei Li* Org. Lett. 2016, 18, 3662-3665.

12.   “Ru(II)-Catalyzed C-H Activation of Imidamides and Divergent Couplings with Diazo Compounds: Substrate-Controlled Synthesis of Indoles and 3H-Indoles” Yunyun Li, Zisong Qi, He Wang, Xifa Yang, Xingwei Li* Angew. Chem. Int. Ed. 2016, 55, 11877-11881.

13.  “Synthesis of Cyclopentadienols by Rhodium-Catalyzed C-H Activation of 8-Formylquinolines and [2+2+1] Carbocyclization with Alkynes” Xingwei Li*, Xifa Yang, Zisong Qi, ACS Catal. 2016, 6, 6372-6376.

14.  “Rhodium(III)-Catalyzed Regio- and Stereo-selective C-H Allylation of Arenes with Vinyl Benzoxazinanones” Zisong Qi, Lingheng Kong, Xingwei Li* Org. Lett. 2016, 18, 4392-4395. (highlighted by Synfacts)

15.  “Transition Metal-Catalyzed Couplings between Arenes and Strained or Reactive Rings: Combination of C-H Activation and Ring Scission” Fen Wang, Songjie Yu, Xingwei Li* Chem. Soc. Rev. 2016, 45, 6462-6477. (ESI highly cited)

16.  “Mild Acylation of both C(sp3)-H and C(sp2)-H Bonds under Redox-Neutral Rh(III) Catalysis” Songjie Yu, Yingzi Li, Lingheng Kong, Xukai Zhou, Guodong Tang, Yu Lan*, Xingwei Li* ACS Catal. 2016, 6, 7744-7748.

17.  “Nitrone Directing Groups in Rh(III)-Catalyzed C-H Activation of Arenes: 1,3-Dipoles versus Traceless Directing Groups” Fang Xie, Songjie Yu, Zisong Qi, Xingwei Li* Angew. Chem. Int. Ed. 2016, 55, 15351-15355.

18.   “Rh(III)- and Zn(II)-Catalyzed Synthesis of Quinazoline N-Oxides via C-H Amidation-Cyclization of Oximes” Qiang Wang, Fen Wang, Xifa Yang, Xukai Zhou, Xingwei Li* Org. Lett. 2016, 18, 6144-6147.

19.  “Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes” Lingheng Kong, Xukai Zhou, Xingwei Li* Org. Lett. 2016, 18, 6320-6323.

20.  “Experimental and Theoretical Studies on Rhodium-Catalyzed Coupling of Benzamides with 2,2-Difluorovinyl Tosylate: Diverse Synthesis of Fluorinated Heterocycles” Jia-Qiang Wu, Shang-Shi Zhang, Hui Gao, Zisong Qi, Chu-Jun Zhou, Wei-Wei Ji, Yao Liu, Yunyun Chen, Qingjiang Li, Xingwei Li,* Honggen Wang* J. Am. Chem. Soc. 2017,139, 3537-3545. (ESI highly cited)

21.  “Cobalt(III) and Rhodium(III)-Catalyzed C-H Amidation and Synthesis of 4-Quinolones: C-H Activation Assisted by Weakly Coordinating and Functionalizable Enaminone” Fen Wang, Liang Jin, Lingheng Kong, Xingwei Li* Org. Lett. 2017, 19, 1812-1815.

22.  “Cp*Rh(III)-Catalyzed Mild Addition of C(sp3)–H Bonds to α,β-Unsaturated Aldehydes and Ketones” Bingxian Liu, Panjie Hu, Xukai Zhou, Dachang Bai, Junbiao Chang,* Xingwei Li* Org. Lett. 2017, 19, 2086-2089.

23.  “Catalyst-Controlled Regiodivergent Alkyne Insertion in the Context of C-H Activation and Diels-Alder Reactions: Synthesis of Fused and Bridged Cycles” Xukai Zhou, Yupeng Pan, Xingwei Li* Angew. Chem. Int. Ed. 2017, 56, 8163-8167.

24.  “Iridium(III)-Catalyzed Synthesis of Benzimidazoles via C-H Activation and Amidation of Aniline Derivatives” Jintao Xia, Xifa Yang, Yunyun Li, and Xingwei Li* Org. Lett. 2017, 19, 3243-3246.

25.  “Divergent Access to 1-Naphthols and Isocoumarins via Rh(III)-Catalyzed C-H Activation Assisted by Phosphonium Ylide” Yunyun Li, Qiang Wang, Xifa Yang, Fang Xie, and Xingwei Li* Org. Lett. 2017, 19, 3410-3413.

26.  “Rhodium(III)-Catalyzed Acylation of C(sp3)-H Bonds with Cyclopropenones” Lingheng Kong, Xukai Zhou, Youwei Xu, Xingwei Li* Org. Lett. 2017, 19, 3644-3647.

27.   “Naphthol Synthesis: Annulation of Nitrones with Alkynes via Rhodium(III)-Catalyzed C-H Activation” Qiang Wang, Youwei Xu, Xifa Yang, Yunyun Li, and Xingwei Li* Chem. Commun. 2017, 53, 9640-9643.

28.  “Rhodium(III)-Catalyzed Synthesis of Naphthols via C−H Activation of Sulfoxonium Ylides” Youwei Xu, Xifa Yang, Xukai Zhou, Lingheng Kong, Xingwei Li* Org. Lett. 2017, 19, 4307-4310.

29.  “Rhodium(III)-Catalyzed Regio- and Stereoselective Benzylic a-Fluoroalkenylation with gem-Difluorostyrenes” Lingheng Kong, Bingxian Liu, Xukai Zhou, Fen Wang,* Xingwei Li,* Chem. Commun. 2017, 53, 10326-10329.

30.  “Sulfoxonium Ylides as a Carbene Precursor in Rh(III)-Catalyzed C-H Acylmethylation of Arenes” Youwei Xu, Xukai Zhou, Guangfan Zheng, Xingwei Li* Org. Lett. 2017, 19, 5256-5259.

31.  “Cp*Co(III)-Catalyzed Branch-Selective Hydroarylation of Alkynes via C-H Activation：Efficient Access to α-gem-Vinylindoles”, Xukai Zhou, Yixin Luo, Lingheng Kong, Youwei Xu, Guangfan Zheng, Yu Lan,* Xingwei Li* ACS Catal. 2017, 7, 7296-7304.

32.  “Rh(III)-Catalyzed Diastereodivergent Spiroannulation of Cyclic Imines with Activated Alkenes” Bingxian Liu, Panjie Hu, Yunyun Li, Ying Zhang, Dachang Bai, Xingwei Li* Org. Lett. 2017, 19, 5402-5405.

33.  “Access to Substituted Propenoic Acids via Rh(III)-Catalyzed C−H Allylation of (Hetero)Arenes with Methyleneoxetanones” Jintao Xia, Lingheng Kong, Xukai Zhou, Guangfan Zheng, Xingwei Li*, Org. Lett. 2017, 19, 5972-5975.

34.   “Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation” Xiaohong Chen, Guangfan Zheng, Yunyun Li, Guoyong Song, Xingwei Li*, Org. Lett. 2017, 19, 6184-6187.

35.   “Rhodium(III)-Catalyzed Chemodivergent Annulations between N-Methoxybenzamides and Sulfoxonium Ylides via C-H Activation” Youwei Xu, Guangfan Zheng, Xifa Yang, Xingwei Li*, Chem. Commun. 2018, 54, 670-673. (ESI highly cited)

36.  “Rh(III)-Catalyzed Acceptorless Dehydrogenative Coupling of (Hetero)arenes with 2-Carboxyl Allylic Alcohols”Jintao Xia, Zhipeng Huang, Xukai Zhou, Xifa Yang, Feng Wang, Xingwei Li*, Org. Lett. 2018, 20, 740-743.

37.  “Regio- and Diastereoseletive Access to Fused Isoxazolidines via Ru(II)-Catalyzed C-H Activation of Nitrones and Coupling with Perfluoroalkylolefins” Yunyun Li, Fang Xie, Yuan Liu, Xifa Yang, Xingwei Li* Org. Lett. 2018, 20, 437-440. (highlighted by Synfact, ESI highly cited)

38.  “Access to Quaternary Stereogenic Centers via Rh(III)-Catalyzed Annulations between 2-Phenylindoles and Ketenes” Xifa Yang, Yunyun Li, Lingheng Kong, Xingwei Li*, Org. Lett. 2018, 20, 1957-1960.

39.  “Construction of (Dihydro)Naphtho[1,8-bc]pyrans via Rh(III)-Catalyzed Twofold C-H Activation of Benzoylacetonitriles” Panjie Hu, Bingxian Liu*, Xingwei Li* Org. Lett. 2018, 20, 2160-2163.

40.   “Cp*Co(III)-Catalyzed Amidation of Olefinic and Aryl C-H Bonds: Highly Selective Synthesis of Enamides and Pyrimidones” Yuan Liu, Fang Xie, Ai-Qun Jia,* Xingwei Li* Chem. Commun. 2018, 54, 4345-4348.

41.  “Rh(III)-Catalyzed Mild Coupling of Nitrones and Azomethine Imines with Alkylidenecyclopropanes via C-H Activation: Facile Access to Bridged Cycles” Dachang Bai,* Teng Xu, Chaorui Ma, Xin Zheng, Bingxian Liu, Fang Xie, Xingwei Li* ACS Catal. 2018, 8, 4194-4200.

42.  “Redox-Divergent Synthesis of Fluoroalkylated Pyridines and 2-Pyridones via Cu-Catalyzed N-O Cleavage of Oxime Acetates” Dachang Bai, Xueli Wang, Guangfan Zheng, Xingwei Li* Angew. Chem. Int. Ed.  2018, 57, 6633-6637.

43.  “Divergent Couplings of Anilines and Enones via Integration of C-H Activation and Transfer Hydrogenation” Xukai Zhou, Jintao Xia, Guangfan Zheng, Lingheng Kong, Xingwei Li* Angew. Chem. Int. Ed.  2018, 57, 6681-6685.

44.  “Redox-Neutral Access to Isoquinolinones via Rhodium(III)-Catalyzed Annulations of O-Pivaloyl Oximes with Ketenes” Xifa Yang, Song Liu, Songjie Yu, Lingheng Kong, Yu Lan*, Xingwei Li* Org. Lett. 2018, 20, 2698-2701.

45.   “Ruthenium- and Rhodium-Catalyzed Chemo-Divergent Couplings of Ketene Dithioacetals and α-Diazo Ketones via C-H Activation” Manman Wang, Lingheng Kong, Qiyue Wu, Xingwei Li*, Org. Lett. 2018, 20, 4597-4600.

46.   “Divergent Annulative C-C Coupling Initiated by Mn-Catalyzed C-H Activation of Indoles” Bingxian Liu, Jie Li, Panjie Hu, Xukai Zhou, Dachang Bai, Xingwei Li* ACS Catal. 2018, 8, 9463-9470.

47.  “Rh(III)-Catalyzed C–C Coupling of Diverse Arenes and 4-Acyl-1-Sulfonyltriazoles via C–H Activation” Miaomiao Tian, Bingxian Liu, Jiaqiong Sun, Xingwei Li*, Org. Lett. 2018, 20, 4946-4949.

48.  “Enantiodivergent Annulation of Sulfoximines with Diazo Compounds via Rh(III)-Catalyzed Desymmetrizative C-H Activation” Bingxue Shen, Boshun Wan, and Xingwei Li*, Angew. Chem. Int. Ed. 2018, 57, 15534-15538.

49.  “2H-Chromene-3-Carboxylic Acid Synthesis via Solvent-Controlled and Rhodium(III)-Catalyzed Redox-Neutral C–H Activation/[3+3] Annulation Cascade” Zhi Zhou, Mengyao Bian, Lixin Zhao, Hui Gao, Junjun Huang, Xiawen Liu, Xiyong Yu, Xingwei Li, Wei Yi* Org. Lett. 2018, 20, 3892-3896.

50.   “Enantioselective Copper-Catalyzed Hydroamination of Vinylarenes with Anthranils” Fang Xie, Bingxian Liu, Xingwei Li*, Org. Lett. 2018, 20, 7154-7157.

51.  “Ag(I)-Catalyzed Nucleophilic Addition and Friedel-Crafts Alkylation between α-Oxo Ketene Dithioacetals and Propargyl Carbonates” Manman Wang, Dachang Bai, Lingheng Kong, Bingxian Liu, Xingwei Li, Org. Lett. 2018, 20, 7775-7778.

52.   “Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes via C-H Activation/Desymmetrization” Xifa Yang, Guangfan Zheng, Xingwei Li* Angew. Chem. Int. Ed. 2019, 58, 322-326.  

53.   “Mn-Catalyzed Dehydrocyanative Transannulation of Heteroarenes via C-H Activation: Beyond the Permanent Directing Effects of Pyridines/Pyrimidines” Gangfan Zheng, Jiaqiong Sun, Youwei Xu, Shuailei Zhai, Xingwei Li, Angew. Chem. Int. Ed. 2019, 58, 322-326.  

54.  “Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration” Jiaqiong Sun, Dachang Bai, Peiyuan Wang, Kuan Wang, Guangfan Zheng, Xingwei Li, Org. Lett. 2019, 21, 1789-1793.

55.  “Rhodium(III)-catalyzed diverse [4 + 1] annulation of arenes with 1,3-enynes via sp3/sp2 C–H activation and 1,4-rhodium migration” Dachang Bai, Jintao Xia, Fangfang Song, Xueyan Li, Bingxian Liu, Lihong Liu, Guangfan Zheng, Xifa Yang, Jiaqiong Sun* Xingwei Li*Chem. Sci. 2019, 10, 3987-3993.

56.  “Access to 2-Naphthols via Ru(II)-Catalyzed C-H Annulation of Nitrones with α-Diazo Sulfonyl Ketones” Lingheng Kong, Xi Han, Xingwei Li, Chem. Comun. 2019, 55, 7339-7342.

57.  “Rhodium(III)-Catalyzed Oxidative Allylic C–H Indolylation via Nucleophilic Cyclization” Jiaqiong Sun, Kuan Wang, Peiyuan Wang, Guangfan Zheng,* Xingwei Li* Org. Lett. 2019, 21, 4662-4666.

58.  “Manganese(I)-Catalyzed Synthesis of Fused Eight- and Four-Membered Carbocycles via C–H Activation and Pericyclic Reactions” Youwei Xu, Guangfan Zheng, Lingheng Kong, and Xingwei Li* Org. Lett. 2019, 21, 3402-3406.

59.  “Rh(III)-Catalyzed Asymmetric Synthesis of Axially Chiral Biindolyls by Merging C-H Activation and Nucleophilic Cyclization” Miaomiao Tian, Dachang Bai, Guangfan Zheng, Junbiao Chang, and Xingwei Li* J. Am. Chem. Soc. 2019, 141, 9527-9532.

60.  “Nickel(0)-Catalyzed Enantio- and Chemo-Selective [3+2] Annulation of Cyclopropenones and a,b-Unsaturated Ketones/Imines” submitted to J. Am. Chem. Soc. (revised manuscript).